A number of experiments have been described by Mme Curie in her Thèse présentée à la Faculté des Sciences de Paris on the effect of solution and of heat in diminishing the activity of radium. The results obtained are in general agreement with the above view, that 75 per cent. of the activity of radium is due to the emanation and the excited activity it produces. If the emanation is wholly or partly removed by solution or heating, the activity of the radium is correspondingly diminished, but the activity of the radium compound is spontaneously recovered owing to the production of fresh emanation. A state of radio-active equilibrium is reached, when the rate of production of fresh emanation balances the rate of change in the emanation stored up in the compound. The differences observed in the rate of recovery of radium under different conditions were probably due to variations in the rate of escape of the emanation.
217. It has been shown in section 152 that the emanation is produced at the same rate in the solid as in the solution, and all the results obtained point to the conclusion that the emanation is produced from radium at a constant rate, which is independent of physical conditions. Radium, like thorium, shows a non-separable activity of 25 per cent. of the maximum activity, and consisting entirely of α rays. The β and γ rays arise only from the active deposit. The emanation itself ([section 156]) gives out only α rays. These results thus admit of the explanation given in the case of thorium ([section 136]). The radium atoms break up at a constant rate with the emission of α particles. The residue of the radium atom becomes the atom of the emanation. This in turn is unstable and breaks up with the expulsion of an α particle. The emanation is half transformed in four days. We have seen that this emanation gives rise to an active deposit. The results obtained up to this stage are shown diagrammatically below.
α particle α particle
/ /
/ /
Radium atom ——> atom of Emanation ——> ATOM OF ACTIVE DEPOSIT
218. Analysis of the active deposit from radium. We have seen in [chapter VIII] that the excited activity produced on bodies, by the action of the radium emanation, is due to a thin film of active matter deposited on the surface of bodies. This active deposit is a product of the decomposition of the radium emanation, and is not due to any action of the radiations on the surface of the matter.
The curves showing the variation of the excited activity with time are very complicated, depending not only upon the time of exposure in the presence of the emanation, but also upon the type of radiation used for measurement. The greater portion of the activity of this deposit dies away in the course of 24 hours, but a very small fraction still remains, which then changes very slowly.
It will be shown in this chapter that at least six successive transformations occur in the active deposit. The matter initially produced from the emanation is called radium A, and the succeeding products B, C, D, E, F. The equations expressing the quantity of A, B, C,...... present at any time are very complicated, but the comparison of theory with experiment may be much simplified by temporarily disregarding some unimportant terms: for example, the products A, B, C are transformed at a very rapid rate compared with D. The activity due to D + E + F is, in most cases, negligible compared with that of A or C, being usually less than ¹⁄₁₀₀₀₀₀ of the initial activity observed for A or C. The analysis of the active deposit of radium may thus be conveniently divided into two stages:
(1) Analysis of the deposit of rapid change, which is mainly composed of radium A, B, and C;