| Layers of foil | Current |
| 0 | 100 |
| 1 | 59 |
| 2 | 30 |
| 3 | 10 |
| 4 | 3·2 |
The greater proportion of the conductivity is thus due to α rays, as in the case of the radio-active elements. The amount of absorption of these α rays by aluminium foil is about the same as that of the rays from the active bodies. No direct comparison can be made, for the α rays from the emanation show the characteristic property of increased rate of absorption with thickness of matter traversed. Before testing, the rays have been largely absorbed by the mica window, and the penetrating power has consequently decreased.
No alteration in the radiation from the emanation was observed on placing an insulated wire inside the emanation vessel, and charging it to a high positive or negative potential. When a stream of air through the vessel carried away the emanation as fast as it was produced, the intensity of the radiation fell to a small fraction of its former value.
No evidence of any β rays in the radiations was found in these experiments, although a very small effect would have been detected. After standing some hours, however, β rays began to appear. These were due to the excited activity deposited on the walls of the vessel from the emanation, and not directly to the emanation itself.
The radium emanation, like that of thorium, only gives rise to α rays. This was tested in the following way[[249]]:
A large amount of emanation was introduced into a cylinder made of sheet copper ·005 cm. thick, which absorbed all the α rays but allowed the β and γ rays, if present, to pass through with but little loss. The external radiation from the cylinder was determined at intervals, commencing about two minutes after the introduction of the emanation. The amount observed at first was extremely small, but increased rapidly and practically reached a maximum in three or four hours. Thus the radium emanation only gives out α rays, the β rays appearing as the excited activity is produced on the walls of the vessel. On sweeping out the emanation by a current of air, there was no immediately appreciable decrease of the radiation. This is another proof that the emanation does not emit any β rays. In a similar way it can be shown that the emanation does not give out γ rays; these rays always make their appearance at the same time as the β rays.
The method of examination of the radiations from the emanations has been given in some detail, as the results are of considerable importance in the discussion, which will be given later in chapters [X] and [XI], of the connection between the changes occurring in radio-active products and the radiations they emit. There is no doubt that the emanations, apart from the excited activity to which they give rise, only give out α rays, consisting most probably of positively charged bodies projected with great velocity.
Effect of pressure on the rate of production of the Emanation.
157. It has already been mentioned that the conductivity due to the thorium emanation is proportional to the pressure of the gas, pointing to the conclusion that the rate of production of the emanation is independent of the pressure, as well as of the nature of the surrounding gas. This result was directly confirmed with the apparatus of [Fig. 55]. When the pressure of the gas under the vessel was slowly reduced, the radiation, tested outside the window, increased to a limit, and then remained constant over a wide range of pressure. This increase, which was far more marked in air than in hydrogen, is due to the fact that the α rays from the emanation were partially absorbed in the gas inside the vessel when at atmospheric pressure. At pressures of the order of 1 millimetre of mercury the external radiation decreased, but experiment showed that this must be ascribed to a removal of the emanation by the pump, and not to a change in the rate of production. The thorium compounds very readily absorb water-vapour, which is slowly given off at low pressures, and in consequence some of the emanation is carried out of the vessel with the water-vapour.
Curie and Debierne[[250]] found that both the amount of excited activity produced in a closed vessel containing active samples of radium, and also the time taken to reach a maximum value, were independent of the pressure and nature of the gas. This was true in the case of a solution down to the pressure of the saturated vapour, and in the case of solid salts to very low pressures. When the pump was kept going at pressures of the order of ·001 mm. of mercury, the amount of excited activity was much diminished. This was probably not due to any alteration of the rate of escape of the emanation, but to the removal of the emanation by the action of the pump as fast as it was formed.