(2) Action of hydrofluoric acid upon the hydrates freshly precipitated, and held in suspension in water. The portion dissolved is only slightly active. By this method titanium may be separated.
(3) Precipitation of neutral nitrate solutions by oxygenated water. The precipitate carries down the active body.
(4) Precipitation of insoluble sulphates. If barium sulphate, for example, is precipitated in the solution containing the active body, the barium carries down the active matter. The thorium and actinium are freed from the barium by conversion of the sulphate into the chloride and precipitation by ammonia.
In this way Debierne has obtained a substance comparable in activity with radium. The separation, which is difficult and laborious, has not yet been carried far enough to bring out any new lines in the spectrum.
18. After the initial announcement of the discovery of actinium, several years elapsed before any definite results upon it were published by Debierne. In the meantime, Giesel[[29]] had independently obtained a radio-active substance from pitchblende which seemed similar in many respects to the actinium of Debierne. The active substance belongs to the group of cerium earths and is precipitated with them. By a succession of chemical operations, the active substance is separated mixed with lanthanum. While intensely active in comparison with thorium, the new active substance closely resembles it in radio-active properties, although, from the method of separation thorium cannot be present except in minute quantity. Giesel early observed that the substance gave off a radio-active emanation. On account of the intensity of the emanation it emits, he termed it the “emanating substance.” Recently this name has been changed to “emanium,” and under this title preparations of the active substance prepared by Giesel have been placed on the market.
Giesel found that the activity of this substance was permanent and seemed to increase during the six months’ interval after separation. In this respect it is similar to radium compounds, for the activity of radium, measured by the electric method, increases in the course of a month’s interval to four times its initial value at separation.
There can be no doubt that the “actinium” of Debierne and the “emanium” of Giesel contain the same radio-active constituent, for recent work[[30]] has shown that they exhibit identical radio-active properties. Each gives out easily absorbed and penetrating rays, and emits a characteristic emanation of which the rate of decay is the same for both substances. The rate of decay of the emanation is the simplest method of distinguishing actinium from thorium, which it resembles so closely in radio-active as well as in chemical properties. The emanation of actinium loses its radiating power far more rapidly than that of thorium, the time taken for the activity to fall to half value being in the two cases 3·7 seconds and 52 seconds respectively.
The rapid and continuous emission of this short-lived emanation is the most striking radio-active property possessed by actinium. In still air, the radio-active effects of this emanation are confined to a distance of a few centimetres from the active material, as it is only able to diffuse a short distance through the air before losing its radiating power. With very active preparations of actinium, the material appears to be surrounded by a luminous haze produced by the emanation. The radiations produce strong luminosity in some substances, for example, zinc sulphide, willemite and platinocyanide of barium. The luminosity is especially marked on screens of zinc sulphide. Much of this effect is due to the emanation, for, on gently blowing a current of air over the substance, the luminosity is displaced at once in the direction of the current. With a zinc sulphide screen, actinium shows the phenomena of “scintillations” to an even more marked degree than radium itself.
The preparations of emanium are in some cases luminous, and a spectroscopic examination of this light has shown a number of bright lines[[31]].
The distinctive character of the emanation of actinium, as well as of the other radio-active products to which it gives rise, coupled with the permanence of its activity, renders it very probable that actinium will prove to be a new radio-active element of very great activity. Although very active preparations of actinium have been obtained, it has not yet been found possible to free it from impurities. Consequently, no definite observations have been made on its chemical properties, and no new spectrum lines have been observed.